Overcoming NHCs neutrality: installing tetracarbenes on group 13 and 14 metals.
Identifieur interne : 000092 ( Main/Exploration ); précédent : 000091; suivant : 000093Overcoming NHCs neutrality: installing tetracarbenes on group 13 and 14 metals.
Auteurs : RBID : pubmed:24733683Abstract
The first tetracarbene complexes of group 13 and 14 metals have been synthesized by employing dianionic macrocyclic tetracarbene ligands. The tin, indium, and aluminium tetracarbene complexes are structurally analogous to their porphyrin or salen analogues. The aluminium complex is the first example of multiple NHCs bound to this metal centre.
DOI: 10.1039/c4dt00990h
PubMed: 24733683
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